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Chemistry and Interface Control of Novel 2DPnictogen Nanomaterials

2D-PNICTOCHEM

2D-PnictoChem aims at exploring the Chemistry of a novel class of graphene-like 2D layered elemental materials of group 15, the pnictogens: P, As, Sb, and Bi. In the last few years, these materials have taken the field of Materials Science by storm since they can outperform and/or complement graphene properties. Their strongly layer-dependent unique properties range from semiconducting to metallic, including high carrier mobilities, tunable bandgaps, strong spin-orbit coupling or transparency.

However, the Chemistry of pnictogens is still in its infancy, remaining largely unexplored. This is the niche that 2D-PnictoChem aims to fill. By mastering the interface chemistry, we will develop the assembly of 2Dpnictogens in complex hybrid heterostructures for the first time. Success will rely on a cross-disciplinary approach combining both Inorganic- and Organic Chemistry with Solid-state Physics, including:

  • Synthetizing and exfoliating high quality ultra-thin layer pnictogens, providing reliable access down to the monolayer limit.
  • Achieving their chemical functionalization via both non-covalent and covalent approaches in order to tailor at will their properties, decipher reactivity patterns and enable controlled doping avenues.
  • Developing hybrid architectures through a precise chemical control of the interface, in order to promote unprecedented access to novel heterostructures.
  • Exploring novel applications concepts achieving outstanding performances. These are all priorities in the European Union agenda aimed at securing an affordable, clean energy future by developing more efficient hybrid systems for batteries, electronic devices or applications in catalysis.

The opportunity is unique to reduce Europe’s dependence on external technology and the PI’s background is ideally suited to tackle these objectives, counting as well on a multidisciplinary team of international collaborators.

Host Institution:
Universitat de València
Institute for Molecular Science
Research Team on Molecular Material

Current Members

  • Dr. Gonzalo Abellán – Universitat de València, Spain / Friedrich-Alexander-Universität Erlangen-Nürnberg, Germany (gonzalo.abellan@uv.es)
  • Dr. Matteo Andrea Lucherelli – Universitat de València, Spain (matteo.lucherelli@uv.es)
  • Dra. Rebeca Martínez Haya – Universitat de València, Spain (rebeca.martinez@uv.es)
  • Dra. Cristina Madrona Maqueda – Universitat de València, Spain (cristina.madrona@uv.es)
  • Dra. Edurne Nuin Pla – Universitat de València, Spain (edurne.nuin@uv.es)
  • Dr. Ing. Jorge Romero Pascual – Universitat de València, Spain (jorge.romero@uv.es)
  • Marta Alcaraz Megias – Universitat de València, Spain (marta.alcaraz@uv.es)
  • Camilo Andrés Jaramillo Hernández – Universitat de València, Spain (camilo.jaramillo@uv.es)
  • Pau Congost i Escoin – Universitat de València, Spain (pau.congost@uv.es)
  • Youssra Diouane – Universitat de València, Spain (youssra.diouane@uv.es)
  • Julia Requena – Universitat de València, Spain (jurera@alumni.uv.es)
  • Raúl Serna Guijarro – Universitat de València, Spain (raul.serna@uv.es)
  • Federico Juarez Domínguez – Universitat de València, Spain (federico.juarez@uv.es)
  • Marc López Mollá – Universitat de València, Spain (marclomo@alumni.uv.es)
  • Lucia Fosar Zamora – Universitat de València, Spain
  • Jaime Dorado – Universitat de València, Spain
  • Marta Claramonte – Universitat de València, Spain
  • Christian Olivares Martínez – Universitat de València, Spain (Christian.olivares@uv.es)
  • Maria Del Carmen Serrano Valero – Universitat de València, Spain (maria.c.serrano@uv.es)

Former Members

  • Dr. Mhamed Assebban – Friedrich-Alexander-Universität Erlangen-Nürnberg, Germany (mhamed.assebban@fau.de)
  • Dr. José Alberto Carrasco – Instituto de Tecnología Química, Spain (jocaran1@itq.upv.es)
  • Dr. Christian Dolle – Karlsruhe Institute of Technology, Germany (christian.dolle@kit.edu)
  • Dr. Victor Oestreicher – Universitat de València, Spain (Victor.Oestreicher@uv.es)
  • Dr. Vicente Bernardo Vert Belenguer – Universitat de València, Spain (vicente.vert@uv.es)
  • Dr. Vicent Lloret – Helmholtz Institute Erlangen-Nürnberg for Renewable Energy, Germany (v.llorett@fz-juelich.de)
  • Dr. Stefan Wild – ESK-SiC GmbH, Germany (Stefan.wild@esk-sic.de)
  • Dr. Ing. Jorge Romero – Universitat de València, Spain (jorge.romero@uv.es)
  • Dr. José Alberto Carrasco – Universitat de València, Spain (j.alberto.carrasco@uv.es)
  • Álvaro Seijas Da Silva – Universitat de València, Spain  (alvaro.seijas@uv.es)
  • Michael Fickert – Friedrich-Alexander-Universität Erlangen-Nürnberg, Germany (michael.fickert@fau.de)
  • María Simón – Industrial PhD student, Universitat de Valencia (mariasimon@graphenano.com)
  • Federico Juarez Dominguez – Universitat de València, Spain (fejuado@alumni.uv.es)
  • Raúl Serna Guijarro – Universitat de València, Spain (raul.serna@uv.es)
  • José Ramón Pérez Martínez – Universitat de València, Spain (jorape6@alumni.uv.es)
  • Erik Weinreich – Friedrich-Alexander-Universität Erlangen-Nürnberg, Germany (erik.weinreich@fau.de)
  • Daniel García – Universitat de València, Spain (ibanez@alummni.es)
  • Antonella Gayoso Padula – Universitat de València, Spain (gayoso@alumni.uv.es)
  • Gregoire Thorez – Sorbonne Université, France (gthorez@life.fr)
  • Marta Vegas García – Universitat de València, Spain (marvega2@alumni.uv.es)
  • Constantino Martínez Cocera – Universitat de València, Spain (consmar@alumni.uv.es)
  • Gülüsüm Babayeva -Friedrich-Alexander-Universität Erlangen-Nürnberg, Germany (gulusum.bb.babayeva@fau.de)
  • Mercy Elena Arteaga Vinza – Universitat de València, Spain (mercy_iq@hotmail.com)
  • Julia Requena – Universitat de València, Spain (jurera@alumni.uv.es)
  • Federico Juarez Dominguez – Universitat de València, Spain (fejuado@alumni.uv.es)
  • Raúl Serna Guijarro – Universitat de València, Spain (raul.serna@uv.es)
  • Marc López Mollá – Universitat de València, Spain (marclomo@alumni.uv.es)
  • Rubén Pardo González – Universitat de València, Spain (rupargonalumni@uv.es)
  • Claudia Argente Hernández – Universitat de València, Spain (clauar2@alumni.uv.es)
  • Raquel Vegara Moya – Universitat de València, Spain (ravemo@alumni.uv.es)
  • Marc López Mollá – Universitat de València, Spain (marclomo@alumni.uv.es)
  • Jaime Molina Vaño – Universitat de València, Spain (jaimova@alumni.uv.es)
  • Maira Alejandra Burela Dorado – Universitat de València, Spain
  • Raúl Serna Guijarro – Universitat de València, Spain (raul.serna@uv.es)
  • Isabel Balaguer – Universitat de València, Spain (ibaber@uv.es)
  • Santiago Daniel Gómez Mansilla – Universitat de València, Spain (sangoman@alumni.uv.es)
  • Marta Vega – Universitat de València, Spain (marvero@alumni.uv.es)
  • Santiago Llopis Murcia – Universitat de València, Spain (llomur@alumni.uv.es)
  • Luis Tamarit Isabel – Universitat de València, Spain (luistai@alumni.uv.es)
  • María Ávila Miralles – Universitat de València, Spain (mami8@alumni.uv.es)
  • Jorge Alberto Picazo Aroca – Universitat de València, Spain (jorpia@alumni.uv.es)
  • Carlos Gibaja – Universidad Autónoma de Madrid, Spain (carlos.gibaja@uam.es)
  • Iñigo Torres – Universidad Autónoma de Madrid, Spain (innigo.torres@uam.es)
  • Kevin Synnatschke – University of Heidelberg, Germany (kevin.synnatschke@pci.uni-heidelberg.de)
  • Ana Alemany Domenech – CIPFP Vicente Blasco Ibáñez, Spain (anaalemanydomenech@gmail.com)
  • Christian Olivares Martínez – CIPFP Vicente Blasco, Spain (chrisolblack@mail.com)
  • Alfonso González – Práctica grado superior – CIPFP Vicente Blasco, Spain
  • Marta Lopes Fernández – Práctica grado medio – CIPFP Vicente Blasco, Spain
  • Miriam Fethi Gala – CIPFP Vicente Blasco, Spain (miriamsj0605@gmail.com)
  • Lucía Gil Sanchiz – Universitat de València, Spain(lucia.gil@uv.es)
  • Eva Amparo Jaime Dauden – Universitat de València, Spain (eva.jaime@uv.es

Facilities & Equipment

Clean Room

Clean Room ICMol Building

Vertical Laminar Flow Bench with containment to deliver an ultraclean laminar airflow over a working bench to protect manipulated products from dust, from environment contamination and from cross contamination in the working area. All over pressure zones are surrounded by under negative pressure to prevent any leak back into the room or the clean zones of the cabinet. An additional air flow enters from the front to create an air barrier which brings protection to operator and to lab environment. The unit is provided with two HEPA-14 filters, one for the downflow and another for the exhaust. 70% of the air is recirculated thus minimizing filter clogging and the other 30% is expelled through HEPA-14 filter at top of the unit.

Vertical laminar air flow cabinet Model V70 from Telstar

Vertical Laminar Flow Bench with containment to deliver an ultraclean laminar airflow over a working bench to protect manipulated products from dust, from environment contamination and from cross contamination in the working area. All over pressure zones are surrounded by under negative pressure to prevent any leak back into the room or the clean zones of the cabinet. An additional air flow enters from the front to create an air barrier which brings protection to operator and to lab environment. The unit is provided with two HEPA-14 filters, one for the downflow and another for the exhaust. 70% of the air is recirculated thus minimizing filter clogging and the other 30% is expelled through HEPA-14 filter at top of the unit.

Laminar flow cabinet BC-Technology Type BC-CAU-07-12

Vertical Laminar Flow cabin equipped with active carbon filter to deliver an ultraclean laminar airflow over a working bench to protect manipulated products from dust from environment contamination and from cross contamination in the working area. The active carbon filter allows the operator to work with organic solvents and the additional air flow enters from the front to create an air barrier for vapor solvent flow to the room. The unit is provided with HEPA H14 filter.

  • Michael Fickert – Friedrich-Alexander-Universität Erlangen-Nürnberg, Germany (michael.fickert@fau.de)
  • Álvaro Seijas Da Silva – Universitat de València, Spain (Co-supervised) (alvaro.seijas@uv.es)
  • Marta Alcaraz – Universitat de València, Spain (marta.alcaraz@uv.es)
  • Camilo Andrés Jaramillo Hernández – Universitat de València, Spain (camilo.jaramillo@uv.es)
  • Pau Congost i Escoin – Universitat de València, Spain (pau.congost@uv.es)
  • Youssra Diouane – Universitat de València, Spain (youssra.diouane@uv.es)
  • María Simón – Industrial PhD student, Universitat de Valencia (mariasimon@graphenano.com)
  • Julia Requena – Universitat de València, Spain (jurera@alumni.uv.es)
  • Michael Fickert – Friedrich-Alexander-Universität Erlangen-Nürnberg, Germany (michael.fickert@fau.de)
  • Álvaro Seijas Da Silva – Universitat de València, Spain (Co-supervised) (alvaro.seijas@uv.es)
  • Marta Alcaraz – Universitat de València, Spain (marta.alcaraz@uv.es)
  • Camilo Andrés Jaramillo Hernández – Universitat de València, Spain (camilo.jaramillo@uv.es)
  • Pau Congost i Escoin – Universitat de València, Spain (pau.congost@uv.es)
  • Youssra Diouane – Universitat de València, Spain (youssra.diouane@uv.es)
  • María Simón – Industrial PhD student, Universitat de Valencia (mariasimon@graphenano.com)
  • Julia Requena – Universitat de València, Spain (jurera@alumni.uv.es)
  • Michael Fickert – Friedrich-Alexander-Universität Erlangen-Nürnberg, Germany (michael.fickert@fau.de)
  • Álvaro Seijas Da Silva – Universitat de València, Spain (Co-supervised) (alvaro.seijas@uv.es)
  • Marta Alcaraz – Universitat de València, Spain (marta.alcaraz@uv.es)
  • Camilo Andrés Jaramillo Hernández – Universitat de València, Spain (camilo.jaramillo@uv.es)
  • Pau Congost i Escoin – Universitat de València, Spain (pau.congost@uv.es)
  • Youssra Diouane – Universitat de València, Spain (youssra.diouane@uv.es)
  • María Simón – Industrial PhD student, Universitat de Valencia (mariasimon@graphenano.com)
  • Julia Requena – Universitat de València, Spain (jurera@alumni.uv.es)
  • Michael Fickert – Friedrich-Alexander-Universität Erlangen-Nürnberg, Germany (michael.fickert@fau.de)
  • Álvaro Seijas Da Silva – Universitat de València, Spain (Co-supervised) (alvaro.seijas@uv.es)
  • Marta Alcaraz – Universitat de València, Spain (marta.alcaraz@uv.es)
  • Camilo Andrés Jaramillo Hernández – Universitat de València, Spain (camilo.jaramillo@uv.es)
  • Pau Congost i Escoin – Universitat de València, Spain (pau.congost@uv.es)
  • Youssra Diouane – Universitat de València, Spain (youssra.diouane@uv.es)
  • María Simón – Industrial PhD student, Universitat de Valencia (mariasimon@graphenano.com)
  • Julia Requena – Universitat de València, Spain (jurera@alumni.uv.es)
  • Michael Fickert – Friedrich-Alexander-Universität Erlangen-Nürnberg, Germany (michael.fickert@fau.de)
  • Álvaro Seijas Da Silva – Universitat de València, Spain (Co-supervised) (alvaro.seijas@uv.es)
  • Marta Alcaraz – Universitat de València, Spain (marta.alcaraz@uv.es)
  • Camilo Andrés Jaramillo Hernández – Universitat de València, Spain (camilo.jaramillo@uv.es)
  • Pau Congost i Escoin – Universitat de València, Spain (pau.congost@uv.es)
  • Youssra Diouane – Universitat de València, Spain (youssra.diouane@uv.es)
  • María Simón – Industrial PhD student, Universitat de Valencia (mariasimon@graphenano.com)
  • Julia Requena – Universitat de València, Spain (jurera@alumni.uv.es)
  • Michael Fickert – Friedrich-Alexander-Universität Erlangen-Nürnberg, Germany (michael.fickert@fau.de)
  • Álvaro Seijas Da Silva – Universitat de València, Spain (Co-supervised) (alvaro.seijas@uv.es)
  • Marta Alcaraz – Universitat de València, Spain (marta.alcaraz@uv.es)
  • Camilo Andrés Jaramillo Hernández – Universitat de València, Spain (camilo.jaramillo@uv.es)
  • Pau Congost i Escoin – Universitat de València, Spain (pau.congost@uv.es)
  • Youssra Diouane – Universitat de València, Spain (youssra.diouane@uv.es)
  • María Simón – Industrial PhD student, Universitat de Valencia (mariasimon@graphenano.com)
  • Julia Requena – Universitat de València, Spain (jurera@alumni.uv.es)

Vertical Laminar Flow Bench with containment to deliver an ultraclean laminar airflow over a working bench to protect manipulated products from dust, from environment contamination and from cross contamination in the working area. All over pressure zones are surrounded by under negative pressure to prevent any leak back into the room or the clean zones of the cabinet. An additional air flow enters from the front to create an air barrier which brings protection to operator and to lab environment. The unit is provided with two HEPA-14 filters, one for the downflow and another for the exhaust. 70% of the air is recirculated thus minimizing filter clogging and the other 30% is expelled through HEPA-14 filter at top of the unit.

Vertical Laminar Flow Bench with containment to deliver an ultraclean laminar airflow over a working bench to protect manipulated products from dust, from environment contamination and from cross contamination in the working area. All over pressure zones are surrounded by under negative pressure to prevent any leak back into the room or the clean zones of the cabinet. An additional air flow enters from the front to create an air barrier which brings protection to operator and to lab environment. The unit is provided with two HEPA-14 filters, one for the downflow and another for the exhaust. 70% of the air is recirculated thus minimizing filter clogging and the other 30% is expelled through HEPA-14 filter at top of the unit.

Publications

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22. -«Noncovalent Functionalization and Passivation of Black Phosphorus with Optimized Perylene Diimides for Hybrid Field Effect Transistors»

Lloret , V. , Nuin , E. , Kohring , M. , Wild , S. , Löffler , M. , Neiss , C. , Krieger , M. , Hauke , F. , Görling , A. , Weber , H.B. , Abellán , G. , Hirsch , A.
Advanced Materials Interfaces , 2020 , 7(23) , 2001290

21. -«The Role of Covalent Functionalization in the Thermal Stability and Decomposition of Hybrid Layered Hydroxides»

Oestreicher , V. , Abellán , G. , Coronado , E.
Physica Status Solidi - Rapid Research Letters , 2020 , 14(12) , 2000380

20. -«Quantifying the Covalent Functionalization of Black Phosphorus»

Wild , S. , Dinh , X.T. , Maid , H. , Hauke , F. , Abellán , G. , Hirsch , A.
Angewandte Chemie - International Edition , 2020 , 59(45) , pp. 20230–20234

19. -«Mechanical cleaning of graphene using in situ electron microscopy»

Schweizer , P. , Dolle , C. , Dasler , D. , Abellán , G. , Hauke , F. , Hirsch , A. , Spiecker , E.
Nature Communications , 2020 , 11(1) , 1743

18. -«Two-Dimensional Antimony Oxide»

Wolff , S. , Gillen , R. , Assebban , M. , Abellán , G. , Maultzsch , J.
Physical Review Letters , 2020 , 124(12) , 126101

17. -«Insights into the formation of metal carbon nanocomposites for energy storage using hybrid NiFe layered double hydroxides as precursors»

Romero , J. , Varela , M. , Assebban , M. , Oestreicher , V. , Guedeja-Marrón , A. , Jordá , J.L. , Abellán , G. , Coronado , E.
Chemical Science , 2020 , 11(29) , pp. 7626–7633

16. -«Unveiling the oxidation behavior of liquid-phase exfoliated antimony nanosheets»

Assebban , M. , Gibaja , C. , Fickert , M. , Torres , I. , Weinreich , E. , Wolff , S. , Gillen , R. , Maultzsch , J. , Varela , M. , Tan Jun Rong , S. , Loh , K.P. , Michel , E.G. , Zamora , F. , Abellán , G.
2D Materials , 2020 , 7(2) , 025039

15. -«Fundamental Insights into the Covalent Silane Functionalization of NiFe Layered Double Hydroxides»

Carrasco , J.A. , Seijas-Da Silva , A. , Oestreicher , V. , Romero , J. , Márkus , B.G. , Simon , F. , Vieira , B.J.C. , Waerenborgh , J.C. , Abellán , G. , Coronado , E.
Chemistry - A European Journal , 2020 , 26(29) , pp. 6504–6517

14. -«Boosting the Supercapacitive Behavior of CoAl Layered Double Hydroxides via Tuning the Metal Composition and Interlayer Space»

Seijas-Da Silva , A. , Sanchis-Gual , R. , Carrasco , J.A. , Oestreicher , V. , Abellán , G. , Coronado , E.
Batteries and Supercaps , 2020 , 3(6) , pp. 499–509

13. -«Few-layer Black Phosphorous Catalyzes Radical Additions to Alkenes Faster than Low-valence Metals»

Tejeda-Serrano , M. , Lloret , V. , Márkus , B.G. , Simon , F. , Hauke , F. , Hirsch , A. , Doménech-Carbó , A. , Abellán , G. , Leyva-Pérez , A.
ChemCatChem , 2020 , 12(8) , pp. 2226–2232

12. -«Layered double hydroxide nanocomposites based on carbon nanoforms»

Abellán , G. , Carrasco , J.A. , Coronado , E.
In Layered Double Hydroxide Polymer Nanocomposites
Elsevier 2020 , 411–460

Read the latest news

Track events, lean about activities and get vacation tips for your stay with us.

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Bottom-up nanofabrication of bidimensional pnictogens: a molecular approach

We are pleased to inform that our recent project “Bottom-up nanofabrication of bidimensional pnictogens: a molecular approach” , has been funded by the Ministry of Science and Innovation from the Spanish Government. The time span of this project will be three years and will focus on exploring new approaches for the synthesis , characterization and application of novel 2D pnictogens with controlled morphologies.

Liquid phase exfoliation of antimonene: systematic optimization, characterization and electrocatalytic properties

Take a look at our most recent paper published in Journal of Materials Chemistry A in collaboration with the group of Prof. Félix Zamora (Universidad Autónoma de Madrid)! Herein a systematic study based on liquid phase exfoliation has been developed to optimize antimonene production in terms of concentration and dimensional anisotropy. In this context , we describe the most relevant experimental factors affecting the exfoliation.

New PhD student joins the 2D-Chem family

Marta Alcaraz , graduated in Chemistry from the University of Granada and MSc in Organic Chemistry from the University of Valencia , joins the 2D-Chem team as a new PhD student. She will combine her knowledge on organic chemistry with the 2D systems developed in our group in the search for new functionalized materials.

El ICMol y la AVI promueven envases 100% aislantes y reciclables contra el desperdicio de comida

Disponer de un tipo de “envase-barrera” que facilite la conservación de los alimentos el máximo tiempo posible es uno de los grandes anhelos de las cadenas de distribución. Los productores tratan con ello de mejorar las prestaciones de sus productos , pero también dar respuesta a los consumidores y su creciente exigencia de envases eco-diseñados y alineados con el desarrollo sostenible.

La Estrategia Europea de Plásticos y Economía Circular prevé que en 2030 el 100% de los envases empleados en los estados miembros deben ser reciclables , reutilizables o compostables. Se trata de uno de los grandes retos actuales de la industria.…

Contact

We are a multidisciplinary research group working in four main research lines:

  • Energy storage and conversion
  • Layered hydroxides
  • Carbon nanoforms and hybrid materials
  • 2DPnictogens

One of our main focus is the technology transfer, including the creation of spin-offs like Matteco (www.matteco.com).

We have close links with other recognized scientific groups, being coordinators of different international projects, collaborating with groups and companies all over the world.

If you are interested in doing a collaboration, doing a PhD, work with us, or if you just want more information about us, pls fill the form below.